| dc.contributor.author | Ambeg Paramarta, Adlina | |
| dc.description.abstract | In the recent decade, there has been increasing interest in using renewable feedstocks as chemical commodities for composites and coatings application. Vegetable oils are promising renewable resources due to their wide availability with affordable cost. In fact, the utilization of vegetable oils to produce composite and coatings products has been around for centuries; linseed oil was widely used for wide variety of paints. However, due to its chemical structure, the application of vegetable oils for high-performance materials is limited; and thus chemical modification is necessary. One of the modification approaches is by substituting the glycerol core in the triglycerides with sucrose to form sucrose esters of vegetable oil fatty acids, in which this resin possesses a higher number of functional group per molecule and a more rigid core.
In this research, thermosets of highly functionalized sucrose esters of vegetable oils were developed. Two crosslinking methods of epoxidized surcrose soyate (ESS) resins were explored: direct polymerization with anhydride moieties for composite applications and Michael-addition reaction of acrylated-epoxidized sucrose soyate (AESS) for coatings applications. In the first project, it was shown that the reaction kinetics, thermal and mechanical properties of the materials can be tuned by varying the molar ratio between the epoxide and anhydride, plus the type and amount of catalyst. Furthermore, the toughness properties of the ESS-based thermosets can be improved by changing the type of anhydride crosslinkers and incorporating secondary phase rubbers. Then, in the second system, the epoxy functionality in the ESS was converted into acrylate group, which then crosslinked with amine groups through the Michael-addition reaction to produce coatings systems. The high number of functional groups and the fast reactivity of the crosslinker results in coatings that can be cured at ambient temperature, yet still possess moderately high glass transition temperatures. | en_US |
| dc.publisher | North Dakota State University | en_US |
| dc.rights | NDSU Policy 190.6.2 | |
| dc.title | High Performance Bio-Based Thermosets for Composites and Coatings | en_US |
| dc.type | Dissertation | en_US |
| dc.type | Video | en_US |
| dc.date.accessioned | 2016-11-18T18:24:57Z | |
| dc.date.available | 2016-11-18T18:24:57Z | |
| dc.date.issued | 2016 | |
| dc.identifier.uri | http://hdl.handle.net/10365/25860 | |
| dc.description.sponsorship | National Science Foundation (NSF) Structural Materials and Mechanics program (Grant number CMMI-1130590) | en_US |
| dc.description.sponsorship | National Science Foundation (NSF) and ND-EPSCoR for Center of Sustainable Materials Program (Grant No. IIA-1355466) | en_US |
| dc.rights.uri | https://www.ndsu.edu/fileadmin/policy/190.pdf | |
| ndsu.degree | Doctor of Philosophy (PhD) | en_US |
| ndsu.college | Science and Mathematics | en_US |
| ndsu.department | Coatings and Polymeric Materials | en_US |
| ndsu.program | Coatings and Polymeric Materials | en_US |
| ndsu.advisor | Webster, Dean C. | |
