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State-Space Randles Cell Model for Instrument Calibration

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Fonseca, Aaron James
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State-Space Randles Cell Model for Instrument Calibration (919.5Kb)
Abstract
It is desirable to calibrate electrochemical impedance spectroscopy (EIS) instrumentation using a Randles circuit. This presents a challenge as realistic loads, simulated by this circuit, contain theoretical components (Warburg elements) that are difficult to model. This thesis proposes a state-space solution to this problem and explores the process of realizing a digital high-accuracy approximation of a Randles circuit for the purposes of verifying and calibrating EIS instrumentation. Using Valsa, Dvo{\v r}{\'a}k, and Friedl's network approximation of a Warburg element, a collection of state-space relations describing the impedance of a Randles circuit are derived. From these equations the process of realizing a digital system is explored; this includes a discussion on methods of discretization, an overview of the challenges of realizing digital filters, and an analysis of the effects that finite word-length has on the accuracy of the model when using fixed-point hardware.
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https://hdl.handle.net/10365/31790
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Student Focused, Land Grant, Research Institution

  • Campus Map
    • Campus Map (pdf)
    • Building list
    • Campus Offices
  • Equity
  • Employment
  • Phone/Email Directory
  • Online Services
    • Blackboard
    • One Stop
    • Campus Connection
    • IT Help Desk
    • Libraries
    • Email
    • Student Success Collaborative
  • Registration And Records
    • Course Schedule
    • Dates and Deadlines
North Dakota State University - Libraries
Circulation: (701) 231-8888 | Reference: (701) 231-8886
Administration: (701) 231-8753
Main Library address: 1201 Albrecht Boulevard
Mailing address: Dept #2080 PO Box 6050, Fargo, ND 58108-6050
Site manager: Site manager
Contact Us |