| dc.contributor.author | Zhang, Dawei | |
| dc.description.abstract | Epoxy resin has been exclusively used in many civil engineering applications such as adhesive joints and anti-corrosive coatings, but most of the usages of epoxy resin highly rely on a solid adhesive bonding between the epoxy matrix and the substrate material. In order to improve the bonding performance of epoxy resin, carbon nanotubes (CNTs) are incorporated into the epoxy resin due to their extraordinary mechanical properties. Although CNTs are expected to be promising additives for epoxy resin, the reinforcing efficiency of CNTs is still far from satisfactory, the bonding performance of CNT reinforced epoxy composites remains an essential research issue. In this dissertation, a systematic study was carried out to investigate the bonding performances of epoxy-based composites reinforced using CNTs. The influences of two main influential parameters (surface roughness and bondline thickness) on the bonding performance of epoxy-based composites were examined. It was found that rougher steel substrates or thinner epoxy bondlines yielded better bonding performances for both unreinforced and CNT reinforced epoxy composites. However, according to the SEM image analyses, the reinforcing efficiency of CNTs was restricted by the non-uniform dispersion of CNTs in the epoxy matrix resulted from CNT agglomeration and entanglement. Given that the great variances of CNT geometries may inevitably result in extensive differences on CNT dispersion status and reinforcing efficiencies in CNT reinforced epoxy composites, the dispersion characterizations and bonding performance of CNT reinforced epoxy composites with different CNT geometries were studied. The experimental results indicated that CNTs with larger diameter (50-100 nm) had a greater ability to achieve more uniform dispersion which further led to better bonding performance. Although CNT length did not have an evident effect on the CNT dispersion, epoxy-based composites reinforced by normal-length CNTs (5-20 μm) had higher bonding strength and toughness than those by shorter CNTs (0.5-2 μm). To further improve the dispersion effectiveness of CNTs, a novel CNT mixing method using carboxymethyl cellulose (CMC) was proposed. It was proved that better CNT dispersion resulted from the CMC surface treatment significantly improved the bonding performance of CNT reinforced epoxy composites. | en_US |
| dc.publisher | North Dakota State University | en_US |
| dc.rights | NDSU policy 190.6.2 | en_US |
| dc.title | Bonding Performances of Epoxy-Based Composites Reinforced by Carbon Nanotubes | en_US |
| dc.type | Dissertation | en_US |
| dc.date.accessioned | 2024-03-21T22:55:28Z | |
| dc.date.available | 2024-03-21T22:55:28Z | |
| dc.date.issued | 2022 | |
| dc.identifier.uri | https://hdl.handle.net/10365/33746 | |
| dc.subject | bonding performance | en_US |
| dc.subject | bondline thickness | en_US |
| dc.subject | carbon nanotubes | en_US |
| dc.subject | dispersion characterizations | en_US |
| dc.subject | epoxy-based composites | en_US |
| dc.subject | surface roughness | en_US |
| dc.identifier.orcid | 0000-0002-0277-6342 | en_US |
| dc.rights.uri | https://www.ndsu.edu/fileadmin/policy/190.pdf | en_US |
| ndsu.degree | Doctor of Philosophy (PhD) | en_US |
| ndsu.college | Engineering | en_US |
| ndsu.department | Civil, Construction, and Environmental Engineering | en_US |
| ndsu.advisor | Huang, Ying | |
