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Now showing items 81-87 of 87
Synthesis and Photophysics of Platinum(II) Terdentate and Bidentate Complexes.
(North Dakota State University, 2010)
Platinum(ll) terdentate and bidentate complexes possess square-planar d8 configuration.
The moderate metal-to-ligand charge-transfer (1MLCT) absorption, 3MLCT emission, and
broadband excited-state absorption are the ...
Mechanistic Investigation of Catalytic Chlorite Decomposition by Chlorite Dismutase
(North Dakota State University, 2021)
Water purification processes often involve chlorine-based disinfectants which consequently leads to formation of chloro oxyanions (ClOx−), potent water-soluble oxidizing agents. These chlorine species are kinetically stable ...
Interactions of Synthetic Metal Porphyrinates with PhuS, a Cytoplasmic Heme Trafficking Protein from Pseudomonas aeruginosa
(North Dakota State University, 2010)
Pseudomonas aeruginosa is an opportunistic, Gram negative, bacterial pathogen
that commonly establishes infection in immunocompromised individuals. It contains
protein-based, iron uptake pathways that target both heme ...
Differential Modulation of the Structural and Functional Characteristics of Human Matrix Metalloproteinase Isozymes upon Binding to Different Ligands
(North Dakota State University, 2010)
Matrix metalloproteinases (MMPs) are a family of Zn2
+ -dependent, Ca2
+ -containing
endoproteinases involved in tissue remodeling and degradation of the extracellular matrix
(ECM). Human MMP isozymes are known to be ...
Regioselective and Enantioselective Nitrone Cycloadditions to Alkynones.
(North Dakota State University, 2010)
There has been a need in agriculture, medicine, and organic chemistry for enantiopure
isoxazolines. A direct method for their synthesis is from the cycloaddition of 1,3-dipoles
and alkynes. Alkynones are difficult ...
Influence of Active Site Ligands and Nanoparticle Surfaces on Human Carbonic Anhydrase Isozymes
(North Dakota State University, 2010)
Carbonic anhydrase (CA) is an ubiquitously distributed zinc containing metallo
enzyme that catalyzes the reversible hydration of carbon dioxide to form bicarbonate and a
proton. Existence of 16 isoenzymes of CA in the ...
Diastereoselective Conjugate Radical Additions to ~-Pyrones
(North Dakota State University, 2009)
A convenient protocol for functionalization of ~-pyrones has been developed.
Conjugate radical addition and tandem addition-trapping protocols allowed accessing
highly substituted pyrones in a single operation with high ...